I don't really play the raid, so this current Corrupted Vibranium event has been my only personal experience with Discordant Gear. As I've been save scumming to get specific pieces for each hero, I noticed that for the status perk on melee/ranged pieces, it seems as if the first attack/weapon granting that status effect will always be the same, making certain attack combinations for the status perk impossible if there are more than 2. For example:

1. For melee gear, I always see light combo finisher as the 1st of the 2 attacks. I've never seen other combinations (so no Heavy Combo Finisher Signature Attack for someone like Black Panther or Signature and Power attacks for Kate).
2. For Black Widow's and both Hawkeyes' ranged pieces, it's always Pistol Shot and Razor Arrows, respectively. So it seems you can never get Full Auto High Caliber for Widow, or something like Cluster Pulsar arrows for Hawkeye.

Are these actually the case? Or do I have crazy bad RNG? Kinda bummed that the combinations for the status perks seem a bit limited. Also, can anyone confirm whether or not Kate's Discordant melee gear can drop with Signature attack? Or can it only be Light Combo Finisher Heavy Combo Finisher or Power attack?